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17.03.2017 в РЦ ОЛМИВ состоялся визит сотрудников отдела научно-технической экспертизы Государственного Эрмитажа: Гавриленко Л.С.Ю Григорьева И.А., Чугунова К.С. и Одриковская А.Ю. Обсуждались вопросы научно-технического сотрудничества.

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Journal of Structural Chemistry. Vol. 58, No. 2, March 2017, pp. 399-405

S. V. Paston, A. M. Polyanichko, O. V. Shulenina

STUDY OF DNA INTERACTIONS WITH Cu²⁺ AND Mg²⁺ IONS IN THE PRESENCE OF CAFFEINE

Journal of Structural Chemistry. Vol. 58, No. 2, March 2017, pp. 399-405

DOI: 10.1134/S0022476617020263

A study of caffeine effects on the complexation of the DNA molecule with Cu²⁺ and Mg²⁺ ions in solution is presented. DNA binding with cations and caffeine is traced from changes in DNA circular dichroism and UV absorption spectra. The complexation of caffeine with M²⁺ ions is studied by IR spectroscopy. Caffeine is found to form complexes of different structure with Mg²⁺ and Cu²⁺ ions in solution. In the presence of caffeine, DNA solutions with MCl₂ show signs of formation of intricate complexes involving nitrogenous bases. In DNA solutions with CuCl₂, the presence of caffeine causes additional destabilization of the secondary DNA structure. In DNA solutions with MgCl₂, the presence of caffeine leads to the formation of new complexes with the participation of Mg²⁺, caffeine, and bases without disrupting the secondary DNA structure.

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Materials Chemistry and Physics Volume 189, March 2017, Pages 245-251

D.V. Mamonova, I.E. Kolesnikov, A.A. Manshina, M.D. Mikhailov, V.M. Smirnov

Modified Pechini method for the synthesis of weakly-agglomerated nanocrystalline yttrium aluminum garnet (YAG) powders

Materials Chemistry and Physics Volume 189, March 2017, Pages 245-251

DOI: 10.1016/j.matchemphys.2016.12.025

Modification of Pechini method for synthesis of weakly agglomerated yttrium aluminum garnet powder has been presented. Modified synthesis procedure is based on an additional calcination process in KCl melt at 1000 ˚C and allows obtaining weaker agglomeration of nanoparticles. Structure, morphology and particle size have been defined using scanning electron microscopy technique, X-ray diffraction, and static light scattering. Adsorption ability of powders has also been studied. Diffraction patterns of samples confirm existence of only one YAG phase; the average size of particles is about 200 nm. The size of coherent-scattering regions was determined to be 40−50 nm. Steady-state luminescence properties and lifetimes of nanocristalline YAG:Eu³⁺ powders synthesized by standard and modified Pechini techniques were compared.

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Journal of Non-Crystalline Solids Volume 457, February 2017, Pages 164-168

D.V. Pankin, М.V. Sukhanov, Yu.S. Tveryanovich, М.F. Churbanov

Investigation of structure of GeS_1.35 glasses with the use of isotopically enriched germanium and Raman scattering spectroscopy

Journal of Non-Crystalline Solids Volume 457, February 2017, Pages 164-168

DOI: 10.1016/j.jnoncrysol.2016.11.038

The samples of GeS_1.35 glasses were synthesized with germaniumand sulfur of natural isotopic composition and with isotopically enriched germanium (⁷²Ge, ⁷⁴Ge, ⁷⁶Ge). The glasses were investigated by the method of Raman scattering spectroscopy (RSS). It was shown that GeS_4/2 tetrahedrons and structural units containing Ge-Ge homobonds are present in glasses. The quantum-mechanical calculation of the frequency of fundamental vibrational modes in glass network was carried out. Their dependencies on the atomic mass of germanium were used for identification of bands in RS (Raman scattering) spectra.

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Journal of Luminescence Volume 182, February 2017, Pages 45-48

Nikolay Vasilyev, B.V. Novikov, I.Kh. Akopyan, M.E. Labzovskaya

ZnO-based random lasing on nanoparticles realized by laser induced breakdown

Journal of Luminescence Volume 182, February 2017, Pages 45-48

DOI: 10.1016/j.jlumin.2016.10.012

A simple laser-assisted method to transform metallic Zn to a ZnO-based random lasing medium is reported. The method uses Nd⁺³ laser-induced air breakdown to treat the surface of a Zn target and thus produce ZnO nanoparticles randomly scattered over the broken area. Photoluminescence spectra of some places of the area at room temperature under resonant powerful photoexcitation exhibit the emission band at 395 nm with regularly spacing narrow spikes (<1nm) which is typical of multi-mode lasing. The band is suggested to be originated from electron-hole plasma arising at high excitation in ZnO-based structures. The micro lasers revealed are possibly composed of ZnO nanoparticles scattered in chains inside self-made random resonators, with Zn flinders being mirrors.